Preheat oven to the temperature directed on the brownie package.
Line a 9×13 pan with parchment paper.
Prepare the brownies according to the box directions.
About 4 minutes before the brownies are fully cooked, remove the pan from the oven and evenly top the brownies with the miniature marshmallows.
Return the pan to the oven and bake 4 more minutes to soften the marshmallows.
Remove from the oven and spread the softened marshmallows into an even layer; let the brownies cool completely.
In a microwave-safe bowl, combine the semi-sweet chocolate chips, creamy peanut butter, and unsalted butter.
Microwave on high for 30 seconds, stir, and repeat heating and stirring until the chocolate is melted and the mixture is smooth.
Add the crispy rice cereal and stir to combine.
Drop spoonfuls of the chocolate and peanut butter rice crisp mixture over the marshmallow layer and spread as evenly as possible.
Refrigerate the brownies for at least 2 hours to chill and let the topping set.
Lift the brownies from the pan using the parchment paper and cut into squares.